While Dimitrios faces Le Chiffre aboard his boat Bond uses his charms on Solange to try and found out what Dimitrios is up to.
Bond orders a Mount Gay rum and soda at the bar before asking if he can join the game. After arriving at the One and Only Ocean Club (now known simply as The Ocean Club) Bond heads for the bar where Alex Dimitrios is playing poker. The first drink of the Daniel Craig era is served around half an hour into Casino Royale.